13821Comprehensive organometallic chemistry II : a review of the literature 1982-1994
Treats the use of transition metals in organic synthesis, with an emphasis on synthetically useful transformations on highly functionalized substrates.
13822Comprehensive organometallic chemistry II : a review of the literature 1982-1994
Contents: Lithium, beryllium, and boron groups; Silicon group, arsenic, antimony, and bismuth; Copper and zinc groups; Scandium, yttrium, lanthanides and actinides, and titanium group; Vanadium and chromium groups; Manganese group.
13823Comprehensive organometallic chemistry II : a review of the literature 1982-1994
In addition to providing an updated survey of organometallic compounds of the group 5 elements, these chapters highlight developments in their utilization, most of which have taken place since COMC. Some of the important topics featured include the antitumor activity of vanadocene derivatives; uses in organic synthesis; and a wide variety of catalytic applications, such as the role of group 5 alkylidene complexes in alkene metathesis and ring-opening metathesis polymerization.
13824Comprehensive organometallic chemistry II : a review of the literature 1982-1994
A common theme within this section (Si, Ge and Sn), is the use of bulky groups to stabilize species which are otherwise unknown. This includes the divalent species R2M, the trivalent radicals R3M0, and the multiply-bonded compounds R2M=MR2, R2M=CR2, etc. A significant difference from COMC is the much greater availability of single crystal x-ray diffraction and this is covered. Other important developments covered include, silicone polymers derived from carbofunctional silanes and the developments in polysilane high polymers. The Sn chapter covers the biggest development, the use of organotin compounds in organic synthesis, and this chapter provides the background information.
13825Comprehensive organometallic chemistry II : a review of the literature 1982-1994
This volume covers the advances of organometallic chemistry of cobalt, rhodium and iridium from 1982 to 1993 with over 3,000 references not previously included in COMC. It incorporates recent developments including carbon-hydrogen activation systems and C60 and C70 complexes that have been discovered since the original publication of COMC.
13826Comprehensive organometallic chemistry II : a review of the literature 1982-1994
This volume provides an update on the chemistry of manganese, technetium and rhenium covered in Volume 4 of COMC. The literature surveyed is from 1982 to 1993. The explosive growth in organorhenium chemistry, the use of manganese hydrocarbon complexes in organic synthesis, and the development of the chemistry of high oxidation manganese and rhenium compounds are highlighted. The growth of organotechnetium chemistry which was virtually unknown at the time of COMC is covered in depth.
13827Comprehensive organometallic chemistry II : a review of the literature 1982-1994
In addition to providing an updated survey of organometallic compounds of the group 5 elements, these chapters highlight developments in their utilization, most of which have taken place since COMC. Some of the important topics featured include the antitumor activity of vanadocene derivatives; uses in organic synthesis; and a wide variety of catalytic applications, such as the role of group 5 alkylidene complexes in alkene metathesis and ring-opening metathesis polymerization.
13828Comprehensive organometallic chemistry II : a review of the literature 1982-1994
Following the expansion of the chemistry covered in Volume 1 of COMC, this volume provides the user with an update on COMC and the literature surveyed is from 1982-1993. Volume 1 features the chemistry of Groups 1, 2 and 3 of the periodic table, and the chapters are arranged sequentially following a pattern similar to that in Volume 1 of COMC. One significant difference between the organisation in COMC and COMC II, is that compounds formed between the Group 3 elements and transition metals (including metallaboranes) are now incorporated into Volume 1 (previously they were in Volume 6).
13829Comprehensive organometallic chemistry II : a review of the literature 1982-1994
This volume will include an update (1981-1993) of the chemistry of mono- and bi-nuclear complexes of ruthenium and osmium, with a rather more extensive treatment of tri- and tetra-nuclear complexes. This is because many of the early results in ruthenium and osmium cluster chemistry described in COMC are now much better understood and can thus be placed in a more general context. In the case of complexes containing clusters with five or more metal atoms, the coverage is essentially complete, again because this chemistry has developed during the 1980s.
13830Comprehensive organometallic chemistry II : a review of the litterature 1982-1994
The number of organometallic compounds containing heteronuclear metal–metal bonds has grown tremendously in the last ten years. Also known as cluster compounds, these compounds have been found to exhibit a rich diversity of molecular structures and reactivities. Descriptions of the structures and transformations of the complexes are central features. Separate chapters have been prepared for compounds containing bonds between transition metals and the metals of the copper and zinc subgroups.